Completed: Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 6)

Looking for the teardown or how well the Kentli PH5 battery performs under load? Click the links to learn more.

It’s finally happened – the self-discharge test of the Kentli PH5 Li-ion AA battery has finally come to an end… and it only took almost 3 years!

 

april 29 2018 stats

Kentli PH5 self-discharge test statistics

Self-Discharge Rate

I never anticipated this test would run for so long; although the PH5 did not have a manufacturer-specified self-discharge rate, marketing materials suggested that the batteries had a storage life that was “3-5 times longer than Ni-MH batteries”. Wikipedia states that after one year, normal Ni-MH batteries lose about 50% of their capacity, and low-self-discharge (LSD) Ni-MH batteries lose 15-30%.

Correlating this with the data collected from the Texas Instruments bq27621-G1 fuel gauge, the battery lost 40% of its charge within one year, placing it in between the standard and LSD Ni-MH chemistries. Using Excel’s SLOPE() function, the self-discharge rate was calculated to be 0.10108%/day.

Experimental Improvements

There is some error in State of Charge measurement when using the bq27621 fuel gauge. As it uses the Impedance Track algorithm, open-circuit voltage is used to determine a battery’s state of charge upon gauge initialization. This OCV curve is chemistry-specific, with slightly different formulations requiring different chemistry ID codes. The bq27621 has a fixed Chemistry ID of 0x1202 (LiCoO2/LCO cathode, carbon anode), but experimental data revealed a better-matched Chemistry ID of 0x3107, 0x1224 or 0x0380; the first two chemistries pointed towards a LiMnO4/LMO cathode chemistry which I was somewhat skeptical of, but did not test further.

Using another gauge with a different, programmable Chemistry ID could have led to a straighter SoC curve. This wouldn’t be too difficult to reproduce, as the battery voltage can be fed to the gauge in order to recompute the state of charge. Additionally, the bq27621 has a Terminate Voltage of 3.2 volts (the gauge considers this voltage to be the point in which it reads 0% SoC), which is higher than the battery’s protection voltage of 2.4 volts (granted, there is very little charge difference in this area of the discharge curve).

My test setup was not temperature-controlled; I live in a house without air conditioning and room temperatures can vary from 15 to 35 degrees C (59 to 95 degrees F), depending on the season. However, I doubt that this would have had too much impact on discharge rate, and this would better represent real-life scenarios where a constant temperature may not necessarily be guaranteed.

Finally, this test was performed on a new, uncycled battery. I suspect the discharge rate would be significantly higher on an aged battery that was subject to a lot of charge cycles and day-to-day wear.

Conclusion

This was the longest-running experiment I’ve ever conducted on this blog. The Kentli PH5’s self-discharge rate lasts longer than a standard Ni-MH battery, but a LSD (low-self-discharge) Ni-MH battery would still last longer, albeit with a lower terminal voltage. The battery, when new, should be expected to last almost 3 years without a charge (although there won’t be any charge left by then); it will hold about 60% of its capacity after 1 year of storage.

To download a copy of the self-discharge test data, click here.

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Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 5)

It’s amazing – 894 days (and counting) have elapsed since the start of my long-term experiment, documenting the real-world self-discharge behavior of the Kentli 1.5V Li-ion AA battery… and it’s still ongoing! How have things fared so far?

Surprisingly, even after spending nearly 30 months on the shelf, there is still 12% capacity left. The voltage has dropped from 4.216 to 3.692 volts according to my bq27621 Li-ion fuel gauge; the State of Charge (SoC) has dropped 50% since my last update.

november 28 2017 stats

The linear end date prediction is holding pretty steady, having changed slightly to an estimated 0% charge date somewhere in February 2018.

On that note, I’m impressed by how much attention this little battery has received, even years after my initial review. Every day I see a handful of views checking out the teardown and performance metrics, and there seems to be hardly any sign that this will change anytime soon. To everyone who stops by to check out my blog posts: thank you! 🙂

Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 4)

“It’s been a long time… How have you been?”

It’s been almost a year since I started my discharge test of the Kentli PH5 Li-ion AA battery, and the battery has lost almost 40% of its capacity due to self-discharge.

The discharge curve has gotten a lot less… linear since the last time I posted a self-discharge update. The battery is down to 62% state-of-charge, and its voltage has dropped down to 3.89 volts. Still, there’s a lot of time left until this battery reaches empty… but when?

I’m no statistician, but doing a linear extrapolation in Excel gives an approximate end date of January 2018, and the SLOPE() function in Excel gives me an average drop of 0.111%/day. Of course, this can easily change over the course of this test, but only time will tell…

Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 3)

Aw what, it’s October already? So much for having another blog post in September…
But anyway, “more months, more data!™”

The voltage of the PH5 has dropped down to 4.093 volts as of today (October 1st, 2015), and its State of Charge is now 93%. There’s just enough data to guess the discharge rate of the PH5: with the currently logged data, the PH5 self discharges at approximately 0.103%/day. At this rate, the cell should last years before finally reaching zero. Looks like this will be a very, very long term test…

(At least that would give me more time to procrastinate write blog posts.)

Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 2)

After my first self-discharge analysis of the Kentli PH5 Li-ion AA battery, I have collected another month’s worth of data.

The battery’s voltage drop has been surprisingly linear. Although I didn’t get the exact day when the bq27621-G1’s State of Charge readout dropped to 99%, it is quite clear that the state of charge is dropping with a fairly steep curve now. That said, because the battery’s voltage is still far away from the ‘flat region’ of the discharge curve, it is difficult to determine when the battery will discharge itself completely at this time.

Self-discharge test of Kentli PH5 1.5V Li-ion AA (Part 1)

As an extension to my previous performance analysis of Kentli’s PH5 Li-ion AA battery, I fully charged an unused PH5 and left it on my desk to self-discharge. Every now and then, a Texas Instruments bq27621-G1 fuel gauge is hooked up to the Li-ion battery terminals (in the case of the PH5, the recessed ring around the 1.5V terminal) and the bq27621’s default settings are used to measure the voltage and state of charge.

I started this test on June 18th, 2015 and will keep taking occasional measurements until the protection IC in the PH5 shuts down.

Since the 18th, the voltage dropped from 4.216 volts down to 4.192 volts as of July 6, 2015; the bq27621’s State of Charge reading remains at 100% for the time being. The voltage drop has been fairly linear so far, but I expect it to taper off as the battery discharges to the Li-ion cell’s “flat region”, and only after that do I expect the cell’s voltage to decline more rapidly.